If by took off "your gloves"...you mean disengaged them from the pressurized, temperature controlled and oxygen filled space suit. Your body would instantly freeze into a gloveless Human Popsicle. All kidding aside, this is what would happen.
Your blood and any possible tissue would push SUPER HARD against your skin and bruise the whole hand, swell, and cause excruciating pains. This is the easy way to explain it, it is kind of complex the way veins, tissue, and the occasional bone moves. It will feel like your hand is going to explode as well.
here is what i think the swell up or fall off or maybe can't use them outer space has hard but far land so its hard to breath touch feel and see there just if you were there now dont take them off cause i think you outfit will deflate and you die
They would freeze off or most likely explode. Because the temperature in space can be -100 to like -1000 degrees (or colder I'm guessing). And outer space is a vacuum, making it more plausible for your blood to boil, then therefore possibly "blowing up" your hands.