What Is a Word That Applies to a Refined Person Who Has and Uses Good Manners?

Answer

There are several words that would apply to a person with good manner and refinement, but the best is 'sophisticated'. Another word of description would be 'refined'. A third would be 'well bred'.
1 Additional Answer
The best word that you can use is that they have etiquette. This means that they are very civilized and know how to behave themselves around others and in formal settings.
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