Topic: Sn1 Reactions
Answers to Common Questions
What is an SN1 reaction?
The SN1 reaction is a two-step reaction in which 1. The leaving group leaves, forming a carbocation. This is the slow step, MORE? Read More »
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What are the basics of SN1 and E1 reactions?
SN1: substitution, nucleophilic, unimolecular. E1: elimination, unimolecular. Often simultaneous, both involve carbocation. Read More »
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What is an SN1 reaction? What can be used?
(continued) reactions have intermediates and a several transition states (TS). Read More »
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Featured Content: Sn1 Reactions
The SN1 reaction is a substitution reaction in organic chemistry. "SN" stands for nucleophilic substitution and the "1" represents the fact that the rate-determining ... More »
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Answers to Other Common Questions
An SN1 reaction will occur if: The substrate can form a relatively stable carbocation (typically from a tertiary carbon) The nucleophile is relatively weak A polar protic solvent is used. An SN2 reaction will occur if: The substrate is with... Read More »
Source: http://wiki.answers.com/Q/What_is_the_difference_between_SN1_and_...
You cannot do Sn1 or Sn2 on an sp2 center. The reaction only works with sp3 centers. It has to do with the way the LUMO on the electrophile is positioned. A LUMO on an sp3 center is a sigma* antibonding orbital - easily attacked by the lone... Read More »
Source: http://wiki.answers.com/Q/Why_are_vinylic_halides_unreactive_in_b...
Increasing the polarity of the solvent increases the reaction rate because the leaving group and carbocation (both very polar species) are better stabilized by polar solvents (like dissolves like). Read More »
Source: http://wiki.answers.com/Q/How_the_solvent_polarity_affects_the_re...
Acetone stop an sn1 reaction because it don't have hydrogen bonding and these are considered polar aprotic. Read More »
Source: http://www.kgbanswers.com/why-does-acetone-stop-an-sn1-reaction/1...
Solvent effects [for SN1 reactions] Since the SN1 reaction involves formation of an unstable carbocation intermediate in the rate-determining step, anything that can facilitate this will speed up the reaction. The normal solvents of choice ... Read More »
Source: http://answers.yahoo.com/question/index?qid=20111211043113AAE3oRo
use the Lavoisier's problems solving method Read More »
Source: http://answers.yahoo.com/question/index?qid=20101103164834AAhaJCE
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